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Dr. Xu Guo Xing Liu Prof. Junqing Yan Prof. Shengzhong Frank Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(69):e202202662
Solar-driven water splitting to produce clean and renewable hydrogen offers a green strategy to address the energy crisis and environmental pollution. Heterostructure catalysts are receiving increasing attention for photocatalytic hydrogen generation. ZnO/ZnS/CdS and ZnO/CdS heterostructures have been successfully designed and prepared according to two different strategies. By introducing a heterointerface layer of ZnS between ZnO and CdS, a Z scheme charge-transfer channel was promoted and achieved superior photocatalytic performance. A highest hydrogen generation rate of 156.7 μmol g−1 h−1 was achieved by precise control of the thickness of the heterointerface layer and of the CdS shell. These findings demonstrated that heterostructures are promising catalysts for solar-driven water splitting, and that heterointerface engineering is an effective way to improve the photocatalytic properties of heterostructures. 相似文献
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2000年以来,中国出境旅游高增长、高消费,影响力不断增大,成为国家外交战略的重要内容,外交效应逐渐显现。通过辨析中国出境旅游外交效应的概念、表现形式和结果,基于10个中国主要出境目的国的旅游互动数据,采用DIF-GMM计量经济模型,实证检验了中国出境旅游外交效应。结果表明,中国通过有序推进ADS协议、加强经济援助、举办“旅游年”活动、实施旅游“制裁”,并积极参与国际制度建设等旅游外交行为,促进了与世界各国的友好交往,维护了自身核心利益,提升了外交软实力和国际影响力。国际旅游反作用于国际关系,对国际关系具有显著的正向促进作用,不仅是国际关系的结果,而且是其重要动因之一。中国出境旅游与政治、经济、社会、文化等联动,多方面提升了中国的国际影响力。 相似文献
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以吉林省最大湿地保留区镇赉县为研究区,基于1980—2018年8期土地利用数据,采用网格分析法研究湿地景观格局变化规律及景观指数与人为干扰度的关系。结果表明:(1)镇赉县湿地面积减少290.7 km2,水体、滩地、沼泽变化率分别为-0.45,-2.97和-4.84 km2·a-1。(2)镇赉县湿地率(PLAND)下降6.1%,且从西北部向东南部逐渐递增;斑块数量(NP)与斑块平均面积(AREA_MN)均呈先上升后下降的趋势,东南部湿地景观破碎化加剧,中部破碎化减缓;湿地连通度的空间分布格局为西北向东南递增,斑块结合度指数(COHESION)在中部地区显著增加,在东南部地区缓慢降低。(3)镇赉县湿地人为干扰度逐渐增强、耕地面积的增加和交通网的扩张是镇赉县湿地面积萎缩、景观破碎化加剧和连通度降低的主要人为原因。人为干扰度与NP呈显著正相关,与PLAND、AREA_MN、COHESION均呈负相关。稳定西南部和东北部耕地中湿地斑块,进一步加强中部湿地水体连通性,排查东南部湿地核心区违规建筑,实施分区治理,加强对镇赉县现有湿地的保护,以期实现区域可持续发展。 相似文献
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Dr. Songlin Xue Dr. W. Ryan Osterloh Xiaojuan Lv Ningchao Liu Yimei Gao Dr. Haitao Lei Dr. Yuanyuan Fang Dr. Zhongti Sun Dr. Peifeng Mei Dr. Daiki Kuzuhara Dr. Naoki Aratani Dr. Hiroko Yamada Dr. Rui Cao Dr. Karl M. Kadish Dr. Fengxian Qiu 《Angewandte Chemie (International ed. in English)》2023,62(17):e202218567
The molecular structure, electrochemistry, spectroelectrochemistry and electrocatalytic oxygen reduction reaction (ORR) features of two CoII porphyrin(2.1.2.1) complexes bearing Ph or F5Ph groups at the two meso-positions of the macrocycle are examined. Single crystal X-ray analysis reveal a highly bent, nonplanar macrocyclic conformation of the complex resulting in clamp-shaped molecular structures. Cyclic voltammetry paired with UV/Vis spectroelectrochemistry in PhCN/0.1 M TBAP suggest that the first electron addition corresponds to a macrocyclic-centered reduction while spectral changes observed during the first oxidation are consistent with a metal-centered CoII/CoIII process. The activity of the clamp-shaped complexes towards heterogeneous ORR in 0.1 M KOH show selectivity towards the 4e− ORR pathway giving H2O. DFT first-principle calculations on the porphyrin catalyst indicates a lower overpotential for 4e− ORR as compared to the 2e− pathway, consistent with experimental data. 相似文献
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Dr. Peng Zhang Qian-Cheng Luo Dr. Zhenhua Zhu Wanrong He Nan Song Junting Lv Xuning Wang Prof. Quan-Guo Zhai Prof. Yan-Zhen Zheng Prof. Jinkui Tang 《Angewandte Chemie (International ed. in English)》2023,62(12):e202218540
The syntheses and magnetic properties of organometallic heterometallic compounds [K(THF)6]{CoI[(μ3-HAN)RE2Cp*4]2} ( 1-RE ) and [K(Crypt)]2{CoI[(μ3-HAN)RE2Cp*4]2} ( 2-RE ) containing hexaazatrinaphthylene radicals (HAN⋅3−) and four rare earth (RE) ions are reported. 1-RE shows isolable species with ligand-based mixed valency as revealed by cyclic voltammetry (CV) thus leading to the isolation of 2-RE via one-electron chemical reduction. Strong electronic communication in mixed-valency supports stronger overall ferromagnetic behaviors in 2-RE than 1-RE containing Gd and Dy ions. Ac magnetic susceptibility data reveal 1-Dy and 2-Dy both exhibit slow magnetic relaxation. Importantly, larger coercive field was observed in the hysteresis of 2-Dy at 2.0 K, indicating the enhanced SMM behavior compared with 1-Dy . Ligand-based mixed-valency strategy has been used for the first time to improve the magnetic coupling in lanthanide (Ln) SMMs, thus opening up new ways to construct strongly coupled Ln-SMMs. 相似文献
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Ya-Kui Sun Jin-Bao Qiao Yu-Meng Xin Qin Zhou Zhi-Hua Ma Hui Shao Yu-Ming Zhao 《Angewandte Chemie (International ed. in English)》2023,62(40):e202310917
Herein, we report a concise and divergent synthesis of the complex hasubanan alkaloids metaphanine and oxoepistephamiersine from commercially available and inexpensive cyclohexanedione monoethylene acetal. Our synthesis features a palladium-catalyzed cascade cyclization reaction to set the tricyclic carbon framework of the desired molecules, a regioselective Baeyer–Villiger oxidation followed by a MeNH2 triggered skeletal reorganization cascade to construct the benzannulated aza[4.4.3]propellane, and a strategically late-stage regio-/diastereoselective oxidative annulation of sp3 C−H bond to form the challenging THF ring system and hemiketal moiety in a single step. In addition, a highly enantioselective alkylation of cyclohexanedione monoethylene acetal paved the way for the asymmetric synthesis of target molecular. 相似文献
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PAN Quan MA Feiyan PU Xinqing ZHAO Manyi WU Qiling ZHAO Na YANG Jun TANG Ben Zhong 《高等学校化学研究》2021,37(1):166-170
In this work,a fluorescent probe(TPEBe-I)was developed for adenosine triphosphate(ATP)detection based on the synergetic effect of aggregation-induced emission and counterion displacement.TPEBe-I gave weak emission in aqueous solution due to the heavy-atom effect of counter iodide ion.However,upon the addition of ATP,the new aggregate complex(TPEBe-ATP)was formed between the cationic unit of TPEBe-I and ATP through electrostatic interactions,which not only restricted the intramolecular motion of luminogen but also eliminated the quenching effect of iodide ion.As a result,the fluorescent light-up detection for ATP was successfully achieved.Moreover,TPEBe-I exhibited high selectivity towards ATP and showed a wide linear detection region towards the logarithm of ATP concentration(5—600μmol/L)with a detection limit of 1.0μmol/L,enabling TPEBe-I as a promising probe for ATP quantitative analysis. 相似文献